A few months back I had the urge to try a lot of new things and one thing was a SSG (static site generator) called 11ty.dev and there was one channel and one website that made it super easy to start.
https://www.youtube.com/@11tyRocks/videos https://11ty.rocks/
I liked it because it showed everything from start to "sure you can build an app with that".
What I want to say is that even guides on how to install ProcessWire, make it more secure, or about hooks or how to "write your own module" would make perfect sense. There is more than enough courses could cover.
As already mentioned... there are few bits and pieces out there, most of them are quite outdated or at least the ProcessWire backend already looks totally different which makes it awkward in some kind to watch those videos.
A new fresh approach sounds really good.
There are tons of topics your course or maybe even courses could offer and talk about.
See @bernhard's videos. They are really great and in full detail while only talking about a specific module.
Haven't thought it through but I personally would provide some basics at least (installation, file and folder structure, some best practices), then maybe something like building a blog or magazine (as mentioned already) and go from there. A blog could have a RestAPI, a custom RSS Feed, and, so, on... oh and there is always: SEO, Online Marketing and Affiliate Marketing.
There could be courses about "Why ProcessWire is perfect for (or) How to do SEO, OM, AM with ProcessWire".
Just outlined a few ideas out of my head.
ProcessWire Basics
Installation
Security
Migration
Updates and Maintenance
How to structure your project
Dos and Dont's
Import a HTML Template/Theme
ProcessWire: Your First Real Project
Blog/Journal/Magazine
Member Area
ProcessWire Advanced
User, User roles, Access rights
How to Hook
How to Customize
How to Whitelabel
How to RestAPI/GraphQL
ProcessWire as Headless CMS
Use VUE, Angular, Svelte, AlpineJS with ProcessWire
Your very first ProcessWire module
How to structure your backend, fields and templates
ProcessWire SEO
PageSpeed
Caching
SEO-related Modules
ProcessWire Setups
Multi-User Setup
Multi-Instance Setup
Multi-Domain Setup
ProcessWire Master Class
...
...
...
My 2 cents for now.